https://nova.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 Raman imaging to identify microplastics released from toothbrushes: algorithms and particle analysis https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53848 Wed 28 Feb 2024 16:26:29 AEDT ]]> Concentrations of potentially toxic and essential trace elements in marketed rice of Bangladesh: Exposure and health risks https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:50533 Mn>Cu>Fe>Mo>Se>Co - and were within their maximum allowable limits. The average concentrations (mg kg−1) of toxic trace elements were as follows: As: 0.17, Cr: 0.18, Ni: 0.55 and Pb: 0.18, while 7% and 40% of the rice samples surpassed, respectively, the EU recommended limits of As and Pb. This study revealed that rice could be a primary exposure pathway of toxic elements, leading to either noncarcinogenic or carcinogenic health problems for daily rice consumers. The non-carcinogenic health risk was mainly associated with As which contributed 77% to the hazard index. The carcinogenic risk measured as incremental lifetime cancer risk (ILCR) was high (>10−4) with As, Cr and Ni, while Pb showed a moderate (<10−4) carcinogenic risk to adults. Rice can substantially be contaminated by trace elements other than As with potential human health risks. Consequently, regular monitoring of the marketed rice grain is demanded, backed up by viable mitigation strategies for reducing toxic elements uptake by rice grains.]]> Wed 28 Feb 2024 15:54:22 AEDT ]]> Biochar application for the remediation of salt-affected soils: Challenges and opportunities https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:42991 100 countries, and their distribution is extensive and widespread in arid and semi-arid regions of the world. In order to meet the challenges of global food security, it is imperative to bring barren salt-affected soils under cultivation. Various inorganic and organic amendments are used to reclaim the salt-affected lands. The selection of a sustainable ameliorant is largely determined by the site-specific geographical and soil physicochemical parameters. Recently, biochar (solid carbonaceous residue, produced under oxygen-free or oxygen-limited conditions at temperatures ranging from 300 to 1000 OC) has attracted considerable attention as a soil amendment. An emerging pool of knowledge shows that biochar addition is effective in improving physical, chemical and biological properties of salt-affected soils. However, some studies have also found an increase in soil salinity and sodicity with biochar application at high rates. Further, the high cost associated with production of biochar and high application rates remains a significant challenge to its widespread use in areas affected by salinity and sodicity. Moreover, there is relatively limited information on the long-term behavior of salt-affected soils subjected to biochar applications. The main objective of the present paper was to review, analyze and discuss the recent studies investigating a role of biochar in improving soil properties and plant growth in salt-affected soils. This review emphasizes that using biochar as an organic amendment for sustainable and profitable use of salt-affected soils would not be practicable as long as low-cost methods for the production of biochar are not devised.]]> Wed 28 Feb 2024 15:22:05 AEDT ]]> Bio-Waste Management in Subtropical Soils of India: Future Challenges and Opportunities in Agriculture https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:42992 Wed 28 Feb 2024 15:21:39 AEDT ]]> Current and emerging methodologies for estimating carbon sequestration in agricultural soils: a review https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:41745 Wed 28 Feb 2024 14:56:53 AEDT ]]> Chemical pollution: a growing peril and potential catastrophic risk to humanity https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:42905 Wed 28 Feb 2024 14:51:26 AEDT ]]> Organic farming: A prospect for food, environment and livelihood security in Indian agriculture https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:43947 Wed 28 Feb 2024 14:45:19 AEDT ]]> Dose–effect of nitrogen regulation on the bioremediation of diesel contaminated soil https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52052 Wed 27 Sep 2023 15:30:20 AEST ]]> Investigation of the physicochemical properties of amine-modified organoclays influenced by system pH and their potential to adsorb anionic herbicide https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52053 Wed 27 Sep 2023 15:29:26 AEST ]]> Real-time monitoring and predictive analysis of VOC flux variations in soil vapor: Integrating PID sensing with machine learning for enhanced vapor intrusion forecasts https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54991 Wed 27 Mar 2024 16:32:43 AEDT ]]> Mesoporous Biopolymer Architecture Enhanced the Adsorption and Selectivity of Aqueous Heavy-Metal Ions https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:45366 Cu (∼95.01 to 90.53%) > Cd (∼92.5 to 55.25%) > Ni (∼80.85 to 50.6%), even in the presence of 0.01/0.001 M of CaCl2 and Na2SO4 as background electrolytes and charged organic molecule under an environmentally relevant concentration (200 μg/L). The maximum adsorption capacities of Ni, Cd, Cu, and Pb were calculated as 2.85 ± 0.08, 6.96 ± 0.31, 16.87 ± 1.50, and 26.49 ± 2.04 mg/g, respectively. HNT-BC@Alg has fast sorption kinetics and maximum adsorption capacity within a short contact time (∼2 h). Energy-dispersive X-ray spectroscopy (EDS) elemental mapping exhibited that adsorbed heavy metals co-distributed with Ca, Si, and Al. The reduction of surface area, pore volume, and pore area of HNT-BC@Alg (after sorption of heavy metals) confirms that mesoporous surface (2–18 nm) supports diffusion, infiltration, and interaction. However, a lower range of mesoporous diameter of the adsorbent is more suitable for the adsorption of heavy-metal ions. The adsorption isotherm and kinetics fitted well with the Langmuir isotherm and the pseudo-second-order kinetic models, demonstrating the monolayer formation of heavy-metal ions through both the physical sorption and chemical sorption, including pore filling, ion exchange, and electrostatic interaction.]]> Wed 20 Mar 2024 15:10:50 AEDT ]]> Controlled release herbicide formulation for effective weed control efficacy https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54881 Wed 20 Mar 2024 13:18:34 AEDT ]]> In situ stabilization of arsenic in soil with organoclay, organozeolite, birnessite, goethite and lanthanum-doped magnetic biochar https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52614 La-Euchar >goethite >HDPB-Z >HDPC-M. Birnessite exhibited great affinity for As and drastically reduced As extractability by more than 90% in all single extractions. The results revealed that HDPC-M, HDPB-Z, La-Euchar, birnessite, and goethite are promising immobilizing agents for in situ stabilization of As in terrestrial environments.]]> Wed 18 Oct 2023 13:47:13 AEDT ]]> Impact of Water Regimes on Minimizing the Accumulation of Arsenic in Rice (Oryza sativa L.) https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52603 Wed 18 Oct 2023 13:37:49 AEDT ]]> Toy building bricks as a potential source of microplastics and nanoplastics https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55320 Wed 15 May 2024 15:39:09 AEST ]]> A modified TOP assay to detect per- and polyfluoroalkyl substances in aqueous film-forming foams (AFFF) and soil https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53573 Wed 15 May 2024 15:05:18 AEST ]]> Investigating Microplastics and Nanoplastics Released from a Rubber Band Used for Orthodontic Treatment with Improved Raman Imaging Algorithms https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54800 Wed 13 Mar 2024 11:41:28 AEDT ]]> Functionalized biochars: Synthesis, characterization, and applications for removing trace elements from water https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52459 Wed 11 Oct 2023 15:00:39 AEDT ]]> Herbicidal weed management practices: History and future prospects of nanotechnology in an eco-friendly crop production system https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55105 Wed 10 Apr 2024 16:00:11 AEST ]]> Novel bio-filtration method for the removal of heavy metals from municipal solid waste https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:41810 40%) and Cd (>20%). Aspergillus heteromorphus based bio-filters was the most efficient to remove Cu and Cr from MSWC (20%). Trichoderma viride, Aspergillus heteromorphus, Rhizomucor pusillus and Aspergillus flavus based bio-filters were equally effective for elicitation of Zn (30%) and Ni (>30%) toxicity. Differential minimum inhibitory concentration, uptake of HMs, bio-sorption capacity of HMs by fungi resulted in unequal efficacy of fungal bio-filters.]]> Wed 07 Feb 2024 17:59:49 AEDT ]]> Comparative values of various wastewater streams as a soil nutrient source https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:43096 Wed 07 Feb 2024 17:17:32 AEDT ]]> Environmentally safe release of plant available potassium and micronutrients from organically amended rock mineral powder https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:46503 Wed 07 Feb 2024 16:39:31 AEDT ]]> Minimizing hazardous impact of food waste in a circular economy – Advances in resource recovery through green strategies https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:47940 Wed 07 Feb 2024 16:37:55 AEDT ]]> Desorption and Migration Behavior of Beryllium from Contaminated Soils: Insights for Risk-Based Management https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:40637 0), enthalpically and entropically influenced. Increasing the incubation period and heat treatment resulted in a decrease of Be desorption and migration. The soil clay content and pH were the primary factors influencing Be desorption, and the results suggested that Be was desorbed from metal oxyhydroxides and surfaces of silicates (e.g., reactive surfaces of clay minerals), organic matters, and soil pores. Because of high Kd values, the mobility of Be was limited, and no exceedances of ecological or human health risk index or guidelines were determined for the current contamination levels at the site. However, Be released from the waste trenches has the ongoing potential to increase Be concentration in the soil.]]> Wed 07 Feb 2024 15:22:49 AEDT ]]> Beryllium in contaminated soils: Implication of beryllium bioaccessibility by different exposure pathways https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:48970 Wed 07 Feb 2024 14:54:53 AEDT ]]> Comparison of ashing and pyrolysis treatment on cadmium/zinc hyperaccumulator plant: effects on bioavailability and metal speciation in solid residues and risk assessment https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:41352 Wed 07 Feb 2024 14:52:18 AEDT ]]> Role of beryllium in the environment: Insights from specific sorption and precipitation studies under different conditions https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52210 2 (amorphous) from ICP standard solution, but a mixture of Be(OH)2 (alpha), Be(OH)2 (beta) and ternary Na/S-Be (ΙΙ)-OH(s) solid phase were formed from BeSO4 solutions. The precipitation of Be started at relatively lower pH at higher concentrations than at the lower Be concentration as indicated by both laboratory data and simulation. Across the pH range, the Be sorption curve was divided into three phases, these being pH 3-6, pH 6-10, and pH > 10, within which sorption of Be with soil was 9-97%, 90-97%, and 66-90%, respectively. Beryllium solubility was limited at pH > 7, but a sorption study with soil showed chemisorption under both acidic and alkaline pH (pH 5.5 and 8) conditions, which was confirmed by FTIR and XPS analysis. At pH 5.5 (specifically relevant to the study site), sorption of Be was 72-95%, in which 77% and 46% Be was respectively sorbed by separated fulvic and humic acid fractions. The irreversible chemisorption mechanism was controlled by SOM at higher pH, and by metal oxyhydroxides at lower pH. Both organic and inorganic components synergistically influence the specific chemisorption of Be at the intermediate pH 5.5 of field soil.]]> Wed 07 Feb 2024 14:46:21 AEDT ]]> Environmental chemistry response of beryllium to diverse soil-solution conditions at a waste disposal site https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52380 12.5 g L−1 (soil/solution), considering higher sorption and limited desorption. Variable surface charges developed by different added ions (competing ions, counter ions, and co-existence of all ions) were not always correlated with Be sorption. However, effects of added ions in Be sorption (increased by counter ions and decreased by competing ions) primarily occurred at low pH, with no noticeable changes at pH > 6 due to the hydration and precipitation behaviour of Be at higher pH. Both laboratory data and modelling indicated the substantial effect of counter ions on increased sorption of Be. Relatively higher amounts of sorption under the co-existence of all added ions were suggested from synergistic actions. Sorption was favourable (KL > 0, and 0 < RL < 1) across all concentrations and temperatures at pH 5.5, and high retention (84–97%) occurred after four desorption cycles indicated specific sorption. The sorption process was exothermic (ΔH > −43 kJ mole−1), while desorption was endothermic (ΔH > +78.4 kJ mole−1). All sorption–desorption reactions were spontaneous (ΔG = −Ve), and executed without any structural deformation (ΔS = nearly zero) of soil particles. However, the effect of temperature on desorption was influenced by the concentrations of Be. Higher retention and different sorption–desorption parameters (Kd-desorption > Kd-sorption; Kf-desorption > Kf-sorption; ndesorption/nsorption < 1) indicate limited mobility of Be and the presence of desorption hysteresis in the studied soil under the experimental conditions.]]> Wed 07 Feb 2024 14:36:35 AEDT ]]> Ultrasound-based advanced oxidation processes for landfill leachate treatment: Energy consumption, influences, mechanisms and perspectives https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52951 Wed 07 Feb 2024 14:35:17 AEDT ]]> Ex situ treatment and residual management of PFAS contaminated environmental media https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51661 Wed 07 Feb 2024 14:30:45 AEDT ]]> Agricultural wastes for brine shrimp Artemia production: a review https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:50508 Wed 07 Feb 2024 14:28:38 AEDT ]]> Functional microbiome strategies for the bioremediation of petroleum-hydrocarbon and heavy metal contaminated soils: A review https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51885 Wed 07 Feb 2024 14:25:54 AEDT ]]> Effect of short-term exposure to air pollution on daily cardio- and cerebrovascular hospitalisations in areas with a low level of air pollution https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54640 Wed 06 Mar 2024 15:11:40 AEDT ]]> Toward In Situ Sequestration of Multicomponent PFAS Using Injectable Adsorbent Suspensions https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54621 Wed 06 Mar 2024 10:53:01 AEDT ]]> Eco-biochemical responses, phytoremediation potential and molecular genetic analysis of Alhagi maurorum grown in metal-contaminated soils https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53426 Wed 03 Apr 2024 14:49:40 AEDT ]]> Experimental and numerical investigation on the effect of frequency combinations on PFOA defluorination by dual-frequency ultrasound coupling persulfate https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55019 Wed 03 Apr 2024 13:23:06 AEDT ]]> A comprehensive physicochemical characterization of zinc oxide nanoparticles extracted from sunscreens and wastewaters https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:50685 Wed 01 May 2024 15:09:13 AEST ]]> Response of Iron and Cadmium on Yield and Yield Components of Rice and Translocation in Grain: Health Risk Estimation https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:39295 1) and carcinogenic risks (CR > 1.0 × 10−4) increased with increasing Cd levels in the soil. The application of Fe decreased the human health risks from rice consumption which is more pronounced in Fe 2.0 than in Fe1.0 treatments. The rice cultivar grown in soil-1 (pH 4.6) showed the highest health risks as compared to soil-2 (pH 6.6) and the Quest cultivar had lower health risks than the Langi cultivar.]]> Tue 31 Oct 2023 11:13:06 AEDT ]]> A Comprehensive Review of the Current Progress of Chromium Removal Methods from Aqueous Solution https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:50383 Tue 31 Oct 2023 08:53:22 AEDT ]]> From celebration to contamination: Analysing microplastics released by burst balloons https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54044 Tue 30 Jan 2024 13:50:18 AEDT ]]> Paint has the potential to release microplastics, nanoplastics, inorganic nanoparticles, and hybrid materials https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54541 Tue 27 Feb 2024 20:41:02 AEDT ]]> Super-resolution imaging of micro- and nanoplastics using confocal Raman with Gaussian surface fitting and deconvolution https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54504 Tue 27 Feb 2024 15:32:02 AEDT ]]> Microplastics and nanoplastics analysis: Options, imaging, advancements and challenges https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54439 Tue 27 Feb 2024 14:00:46 AEDT ]]> Investigating the effect of polarity reversal of the applied current on electrochemical degradation of per-and polyfluoroalkyl substances https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54422 Tue 27 Feb 2024 13:57:48 AEDT ]]> Multigenerational effects of TiO2 rutile nanoparticles on earthworms https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53297 Tue 21 Nov 2023 12:03:36 AEDT ]]> Agronomic Performance of Mung Bean as Affected by Basal Zinc Supply and Cadmium Contamination https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55369 Tue 21 May 2024 09:42:30 AEST ]]> The effects of exogenous organic matter addition on bioaccessibility, adsorption kinetics and fractionation of antimony in soils https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52545 Tue 17 Oct 2023 14:51:51 AEDT ]]> Conducting polymer based visible light photocatalytic composites for pollutant removal: Progress and prospects https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52538 Tue 17 Oct 2023 10:12:50 AEDT ]]> Raman imaging for the analysis of silicone microplastics and nanoplastics released from a kitchen sealant https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52760 Tue 14 Nov 2023 15:32:48 AEDT ]]> In vitro gastrointestinal mobilization and oral bioaccessibility of PAHs in contrasting soils and associated cancer risks: focus on PAH nonextractable residues https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:42048 a]pyrene and benzo[a]pyrene NERs from the solvent-spiked soils, and mobilization of six PAHs and their NERs from the MGP soils. PAH oral bioaccessibility was determined. The incremental lifetime cancer risks (ILCRs), using Si-Org-PBET- and total-extractable PAH concentrations from the MGP soils, were calculated. Sorption kinetics modelling showed that 95% of mobilized PAHs sorbed to the silicone rods within 2–19 h, depending on PAH physico-chemical properties. Total-extractable and Si-Org-PBET extractable PAH concentrations exceeded health investigation levels (3 mg/kg based on benzo[a]pyrene toxic equivalent quotients) in soils. PAH oral bioaccessibility approached 100% for solvent-spiked soils, but only 24–36% for the MGP soils. Associated ILCRs exceeded target levels (10⁻⁵) for one MGP soil, particularly for 2–3 year olds, despite oral bioaccessibility considerations. In contrast, mobilized PAH NERs did not exceed health investigation and ILCR levels, as the NERs were highly sequestered, especially in the MGP soils. PAH nonextractable residues in long-term contaminated soils are unlikely to be mobilized in concentrations that pose cancer risks to humans following soil ingestion, and do not need to be considered in risk assessments.]]> Tue 14 Nov 2023 14:48:37 AEDT ]]> Enhanced removal of petroleum hydrocarbons using a bioelectrochemical remediation system with pre-cultured anodes https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:24008 -1 and which now showed complete removal of this concentration of diesel within 30days was compared to that of a freshly inoculated new anode MFC (showing 83.4% removal of diesel) with a simultaneous power generation of 90.81mW/m2 and 15.04mW/m2 respectively. The behaviour of pre-cultured anodes at a higher concentration of PH (8000mgl-1) was also investigated. Scanning electron microscopy observation revealed a thick biofilm covering the pre-cultured anodic electrode but not the anode from the freshly inoculated MFC. High resolution imaging showed the presence of thin 60nm diametre pilus-like projections emanating from the cells. Anodic microbial community profiling confirmed that the selection for diesel degrading exoelectrogenic bacteria had occurred. Identification of a biodegradative gene (alkB) provided strong evidence of the catabolic pathway used for diesel degradation in the DMFCs.]]> Tue 14 Nov 2023 13:55:11 AEDT ]]> Simultaneous adsorption and biodegradation (SAB) of diesel oil using immobilized Acinetobacter venetianus on porous material https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:24636 80%). Acinetobacter venetianus immobilized on MBC demonstrated superior efficiency in degrading diesel oil (94%) compared to planktonic cells culture (82%) over a 3-day period. Moreover, the simultaneous adsorption and biodegradation of diesel oil using these immobilized cells fitted well to the pseudo second order (R² > 0.99). Scanning electron microscopy (SEM) revealed that through absorption, cells attached well to the cavum of MBC stalk cells. Fourier transform infrared analysis (FTIR) revealed that a large number of bands at 1300-1500 cm-1 existed, demonstrating that the diesel oil was degraded and new bands were formed. Gas Chromatography Mass Spectrum (GC-MS) analysis indicated the immobilized cells could degrade diesel oil into esters and aldehydes. Results justified the applicability of MBC as the carrier matrix for immobilizing microorganisms in removing diesel oil compounds from industrial wastewater.]]> Tue 14 Nov 2023 13:37:32 AEDT ]]> Is paper bag plastic-free, without plastic in colourful logo area? https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55304 Tue 14 May 2024 17:51:02 AEST ]]> Soil properties and organochlorine compounds co-shape the microbial community structure: A case study of an obsolete site https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54213 Tue 13 Feb 2024 11:50:24 AEDT ]]> A review of perchlorate contamination: Analysis and remediation strategies https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51630 Tue 12 Sep 2023 20:07:41 AEST ]]> Evaluating the role of preferential pathways in exacerbating vapour intrusion risks https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52388 Tue 10 Oct 2023 14:45:11 AEDT ]]> Core-Shell Interface-Oriented Synthesis of Bowl-Structured Hollow Silica Nanospheres Using Self-Assembled ABC Triblock Copolymeric Micelles. https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:43124 Tue 07 Nov 2023 15:33:46 AEDT ]]> Unveiling microplastics from zippers: Characterisation and visualisation through Raman imaging analysis https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53498 Thu 30 Nov 2023 15:51:05 AEDT ]]> Review and Perspective: Gas Separation and Discrimination Technologies for Current Gas Sensors in Environmental Applications https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52782 Thu 26 Oct 2023 15:00:47 AEDT ]]> Super-resolution Raman imaging towards visualisation of nanoplastics https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53999 Thu 25 Jan 2024 13:45:38 AEDT ]]> Advancements in Raman imaging for nanoplastic analysis: Challenges, algorithms and future Perspectives https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54294 Thu 15 Feb 2024 14:53:16 AEDT ]]> A Critical Review of Climate Change Impacts on Groundwater Resources: A Focus on the Current Status, Future Possibilities, and Role of Simulation Models https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54648 Thu 07 Mar 2024 15:27:21 AEDT ]]> Bioremediation of mercury: not properly exploited in contaminated soils! (review) https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:26517 Thu 05 Oct 2023 16:40:22 AEDT ]]> Are root elongation assays suitable for establishing metallic anion ecotoxicity thresholds? https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:43512 Thu 02 Nov 2023 14:46:48 AEDT ]]> Arsenic geochemistry and mineralogy as a function of particle-size in naturally arsenic-enriched soils https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:47285 Mon 30 Oct 2023 17:10:01 AEDT ]]> Predicting the quality of air with machine learning approaches: Current research priorities and future perspectives https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52842 Mon 30 Oct 2023 09:46:36 AEDT ]]> Raman imaging combined with an improved PCA/algebra-based algorithm to capture microplastics and nanoplastics https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52823 Mon 30 Oct 2023 09:11:51 AEDT ]]> Magnetically separable mesoporous alginate polymer beads assist adequate removal of aqueous methylene blue over broad solution pH https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38993 intraparticle diffusion (R2 = 0.93) > pseudo-first-order (R2 = 0.87). Energy-dispersive X-ray spectroscopy (EDS) elemental mapping demonstrated that MB has a co-distribution with silicon, aluminium, and alginate carbon phase but is limited with iron and nickel, indicating HNTs and alginate polymer performed as sorption sites, whereas NiZnFe4O4 performed as a catalyst. The presence (post-sorption) and absence (pre-sorption) of inorganic, total carbon or total organic carbon content at different solution pH, contact time, and initial concentration of MB demonstrated that the adsorbent act as a catalyst as well for degradation of MB. NiZnFe4O4-HNT@alg triggers efficient removal of MB with the assist of adsorption and catalytic degradation at broad solution pH. A comparison in removal of MB by various adsorbents including, biochars, clays, activated carbon, nanoparticles, polymers, nano composites, graphene oxides, carbon nanotubes, and polymer beads with the result of this study were performed, illustrating competitive sorption capacity of NiZnFe4O4-HNT@alg.]]> Mon 29 Jan 2024 18:52:42 AEDT ]]> Removal of arsenate from contaminated waters by novel zirconium and zirconium-iron modified biochar https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:39614 Mon 29 Jan 2024 18:47:47 AEDT ]]> Bioaccessibility and speciation of arsenic in children's diets and health risk assessment of an endemic area in Bangladesh https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38254 Mon 29 Jan 2024 18:38:46 AEDT ]]> Magnetic biochar for removal of perfluorooctane sulphonate (PFOS): Interfacial interaction and adsorption mechanism https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:45348 Mon 29 Jan 2024 18:32:06 AEDT ]]> Soil and brownfield bioremediation https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:30778 Mon 29 Jan 2024 18:03:45 AEDT ]]> The influence of different antimony (Sb) compounds and ageing on bioavailability and fractionation of antimony in two dissimilar soils https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38311 8H4K2O12Sb2, Sb2S3, Sb2O3 and Sb2O3 nanoparticles) were evaluated during 120 days ageing time. A black soil (BS) with approximately 12% organic matter (OM) and a red soil (RS) with less than 1% OM were amended with 1000 mg Sb kg−1 of different Sb compounds and subjected to single extractions with distilled (DI) water, 2M HNO3, Simplified Bioaccessibility Extraction Test (SBET) and a modified Community Bureau of Reference (BCR) sequential extraction method. The results revealed that there are substantial variations in dissolution rate of various Sb sources, depending upon soil type and Sb compound. The amounts of DI water extractability of Sb during the incubation time varied between <1% and 2%, whereas HNO3 extractable fractions and Sb bioaccessibility at the end of ageing time ranged between about 1%-3% and <1%–9% of the total Sb, with maximum bioaccessibility observed in BS contaminated with C8H4K2O12Sb2. The residual and labile fractions accounted for 77–93% and 0.1–4% of the total Sb, respectively, indicating that Sb is mostly associated with recalcitrant fractions of the soils. The results of single and sequential extraction studies revealed that source of Sb, ageing time and soil properties can greatly affect the bioavailability of Sb in soils. The findings of this research provide a deeper understanding of the potential risks associated with Sb compounds and highlights the role of site-specific considerations for improving the robustness of toxicity guidelines and long-term management of Sb contaminated sites.]]> Mon 29 Jan 2024 18:01:32 AEDT ]]> Assessing the interactions between micropollutants and nanoparticles in engineered and natural aquatic environments https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38651 Mon 29 Jan 2024 17:49:32 AEDT ]]> Emerging contaminants: A One Health perspective https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55404 Mon 27 May 2024 12:04:23 AEST ]]> Distribution of essential and non-essential elements in rice-based products sold in Australian markets: Exposure assessment https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52555 Mon 22 Apr 2024 14:04:28 AEST ]]> Differential toxicity of potentially toxic elements to human gut microbes https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51765 Cd > Pb > As(III)>As(V) for E. coli; and Hg > Cd > As(III)>Pb > As(V) for the two Lactobacillus sp. Arsenite (AsIII) showed higher toxicity than arsenate (AsV) to gut bacteria. While As is an anion, Cd, Pb and Hg are cations and hence their binding capacity to the bacterial cell wall varied based on the charge dependent functional groups. However, the toxic effects of PTEs for a bacteria are controlled by their speciation and bioavailability.]]> Mon 18 Sep 2023 14:23:29 AEST ]]> Impact of climate change and land use on groundwater hydraulic fluctuations https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52529 Mon 16 Oct 2023 10:52:20 AEDT ]]> Impact of bare and CMC-coated Fe oxide nanoparticles on microbial activity and immobilising zinc, lead, and cadmium in a contaminated soil https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52526 Mon 16 Oct 2023 10:46:17 AEDT ]]> Identification of microplastic fibres released from COVID-19 test swabs with Raman imaging https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52522 Mon 16 Oct 2023 10:45:55 AEDT ]]> The application of rapid handheld FTIR petroleum hydrocarbon-contaminant measurement with transport models for site assessment: a case study https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:37372 Mon 11 Mar 2024 17:41:40 AEDT ]]> Detection of microplastics and nanoplastics released from a kitchen blender using Raman imaging https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52324 Mon 09 Oct 2023 10:23:34 AEDT ]]> Residual hydrocarbons in long-term contaminated soils: implications to risk-based management https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55065 Mon 08 Apr 2024 13:13:26 AEST ]]> Chronic and Transgenerational Effects of Polystyrene Microplastics at Environmentally Relevant Concentrations in Earthworms (Eisenia fetida) https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:46934 50% reduction in juvenile production at 0.5% microplastics concentration in soil. Also, significant genotoxicity in terms of DNA damage was observed in the F0 and F1 earthworms. Chemical analysis of microplastic-exposed soils showed the presence of several benzene derivatives that are associated with polystyrene particles. Our study, for the first time to our knowledge, demonstrated the long-term adverse effects on earthworms of polystyrene microplastics even at environmentally relevant concentrations. The results have significant implications for risk assessment of polystyrene microplastics to soil biota.]]> Mon 06 May 2024 14:06:56 AEST ]]> Degradation of cephalexin toxicity in non-clinical environment using zinc oxide nanoparticles synthesized in Momordica charantia extract; Numerical prediction models and deep learning classification https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51953 90%). These findings reflected the role of deep learning analysis in understanding the behavior of CFX for the degradation process.]]> Fri 22 Sep 2023 17:03:57 AEST ]]> Multicomponent PFAS sorption and desorption in common commercial adsorbents: Kinetics, isotherm, adsorbent dose, pH, and index ion and ionic strength effects https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51936 Fri 22 Sep 2023 12:38:22 AEST ]]> In-vivo (Albino Mice) and in-vitro Assimilation and Toxicity of Zinc Oxide Nanoparticles in Food Materials https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52664 Fri 20 Oct 2023 09:09:38 AEDT ]]> A systematic investigation of single solute, binary and ternary PFAS transport in water-saturated soil using batch and 1-dimensional column studies: Focus on mixture effects https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53860 Fri 19 Jan 2024 12:31:46 AEDT ]]> Influence of biotic and abiotic factors on the development of non-wetting soils and management approaches: A review https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53142 Fri 17 Nov 2023 12:08:21 AEDT ]]> Evaluating PFHxS toxicity to invertebrates and microbial processes in soil https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53106 Fri 17 Nov 2023 11:54:55 AEDT ]]> Sol-Gel Immobilized Optical Microalgal Biosensor for Monitoring Cd, Cu and Zn Bioavailability in Freshwater https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53105 Fri 17 Nov 2023 11:29:40 AEDT ]]> Derivation methods of soils, water and sediments toxicity guidelines: a brief review with a focus on antimony https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:36535 Fri 16 Feb 2024 15:39:29 AEDT ]]> Effects of chelates (EDTA, EDDS, NTA) on phytoavailability of heavy metals (As, Cd, Cu, Pb, Zn) using ryegrass (Lolium multiflorum Lam.) https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51736 Fri 15 Sep 2023 18:07:04 AEST ]]> Investigation of herbicide sorption-desorption using pristine and organoclays to explore the potential carriers for controlled release formulation https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:51710 Fri 15 Sep 2023 14:16:08 AEST ]]> Chemical methods to remove microplastics from wastewater: A review https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:54660 Fri 08 Mar 2024 10:56:33 AEDT ]]> Climate-influenced hydrobiogeochemistry and groundwater remedy design: A review https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53605 Fri 08 Dec 2023 16:08:54 AEDT ]]> Characterising microplastics in indoor air: Insights from Raman imaging analysis of air filter samples https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:55055 Fri 05 Apr 2024 13:53:30 AEDT ]]> Zinc Biofortification through Basal Zinc Supply Reduces Grain Cadmium in Mung Beans: Metal Partitioning and Health Risks Assessment https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52999 Vigna radiata) in two contrast soil types (Dermosol and Tenosol). The soil types with added Zn and Cd exerted a significant effect on translocation and accumulation of metals in different tissues. The accumulation of Zn and Cd was higher for Tenosol than that for Dermosol. At control, the concentration of Cd followed a pattern, e.g., root > stem > petiole > pod > leaflet > grain for both soils. A basal Zn supply (5 mg kg-1) increased the grain Zn concentration to a significant amount (up to 67%). It also reduced Cd accumulation in tissues, including grains (up to 34%). No non-carcinogenic effect was observed for either the children or the adults as the EDI and PTDI values were below the safety limit; however, the ILCR values exceeded the safety limit, indicating the possibility of some carcinogenic effects. Added Zn helped to reduce the carcinogenic and non-carcinogenic health risks on humans.]]> Fri 03 Nov 2023 16:05:28 AEDT ]]> Understanding Iron Impurities in Australian Kaolin and Their Effect on Acid and Heat Activation Processes of Clay https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:52954 Fri 03 Nov 2023 11:04:28 AEDT ]]> Effects of source materials on desorption kinetics of carcinogenic PAHs from contaminated soils https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53514 coal tar > pitch. Increases in Frap of cPAHs were observed in coal tar-treated soils after 48 d soil incubation (0.33%–1.16% for soil M, p ≥ 0.05, 6.24%–9.21% for soil G, p < 0.05) and was attributed to the continuous migration of coal tar as a non-aqueous phase liquid (NAPL) into soil pore structures. Slow desorption was dominated by source materials, whereas the extents and rates of rapid desorption (Frap and krap) were more controlled by the quantity of soil organic matter (SOM), rather than quality of SOM (as in solvent-spiked soils). The results of this study challenged the role of PAH source materials as ‘sinks’ and led to the proposed roles of coal tar and pitch and source materials alike as ‘reservoirs’ with a risk-driven perspective.]]> Fri 01 Dec 2023 10:58:45 AEDT ]]>